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Kinetic studies of homogeneous nitration of toluene
This item is provided by the institution :
National Technical University of Athens
Repository :
Digital Library of National Technical University of Athens | Dspace@NTUA
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ΕΚΤ item type
Journal part
(EN)
Scientific article
(EN)
EKT year
1992
(EN)
EKT historical period
Title
Kinetic studies of homogeneous nitration of toluene (EN)
Creator
Petrolekas, P (EN)
Papayannakos, NG (EN)
Description
The dependence of the nitration rates of toluene in an aqueous phase on reaction temperature and mixed acid composition has been examined. Ternary solutions HNO3-H2SO4-H2O with compositions normally employed in industrial applications have been used as the nitration medium. The activation energy was found to increase with an increase in either the HNO3 content of the nitration medium at constant water content or the H2O content at constant HNO3 content. A kinetic equation is proposed which is applicable over the whole range of conditions used. © 1992 American Chemical Society. (EN)
Type
journalArticle (EN)
Subject
Acid Composition (EN)
Engineering, Chemical (EN)
Chemical Reactions - Thermal Effects (EN)
Sulfuric Acid - Applications (EN)
Activation Energy (EN)
Toluene (EN)
Chemical Reactions - Reaction Kinetics (EN)
Kinetics (EN)
Acids - Mixtures (EN)
Nitric Acid - Applications (EN)
Provider
National Technical University of Athens
Repository / collection
Digital Library of National Technical University of Athens | Dspace@NTUA
Subcollections
Κεντρική Βιβλιοθήκη Ε.Μ.Π.
Ιδρυματικό Αποθετήριο
Δημοσιεύσεις μελών Δ.Ε.Π. σε περιοδικά
Journal
Industrial & Engineering Chemistry Research (EN)
Language
English
Issued
1992 (EN)
Identifier
http://hdl.handle.net/123456789/10726
10.1021/ie00006a006 (EN)
1457 (EN)
0888-5885 (EN)
ISI:A1992HZ06400006 (EN)
6 (EN)
1461 (EN)
31 (EN)
Publisher
AMER CHEMICAL SOC (EN)
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