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Capabilities and limitations of the Wong-Sandler mixing rules
This item is provided by the institution :
National Technical University of Athens
Repository :
Digital Library of National Technical University of Athens | Dspace@NTUA
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ΕΚΤ item type
Journal part
(EN)
Scientific article
(EN)
EKT year
1995
(EN)
EKT historical period
Title
Capabilities and limitations of the Wong-Sandler mixing rules (EN)
Creator
Kalospiros, NS (EN)
Tassios, DP (EN)
Coutsikos, P (EN)
Description
An analysis of the mixing rules proposed by Wong and Sandler (1992) for the attractive and covolume parameter of a cubic equation of state is presented. This set of mixing rules (WS MR) reproduces the correct quadratic composition dependence of the second virial coefficient and, in addition, retains the ability to predict directly high pressure-high temperature phase equilibria from existing low-pressure GE models. It is demonstrated that the proposed mixing rules are valid for symmetric systems, but not for asymmetric ones, where the basic assumptions behind them do not hold anymore. © 1995. (EN)
Type
journalArticle (EN)
Subject
Mixing (EN)
Gibbs free energy (EN)
High temperature high pressure phase equilibria (EN)
Theory (EN)
Excess functions (EN)
Functions (EN)
Mixing rules (EN)
Cubic (EN)
Chemistry, Physical (EN)
Rules (EN)
Thermodynamics (EN)
Engineering, Chemical (EN)
Equations of state (EN)
Vapour/Liquid Systems (EN)
Phase equilibria (EN)
Mathematical models (EN)
Application (EN)
Equation of state (EN)
Provider
National Technical University of Athens
Repository / collection
Digital Library of National Technical University of Athens | Dspace@NTUA
Subcollections
Κεντρική Βιβλιοθήκη Ε.Μ.Π.
Ιδρυματικό Αποθετήριο
Δημοσιεύσεις μελών Δ.Ε.Π. σε περιοδικά
Journal
Fluid Phase Equilibria (EN)
Language
English
Issued
1995 (EN)
Identifier
http://hdl.handle.net/123456789/11466
78 (EN)
59 (EN)
ISI:A1995RE70600005 (EN)
0378-3812 (EN)
1-2 (EN)
108 (EN)
10.1016/0378-3812(94)02675-Q (EN)
Publisher
ELSEVIER SCIENCE BV (EN)
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