A differential method for the analysis of chemical kinetics results based on reversed-flow gas chromatography

 
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1997 (EN)
A differential method for the analysis of chemical kinetics results based on reversed-flow gas chromatography (EN)

Roubani-Kalantzopoulou, F (EN)
Kalantzopoulos, A (EN)
Katsanos, NA (EN)
Kalogirou, E (EN)
Thede, R (EN)
Metaxa, H (EN)
Sotiropoulou, V (EN)

N/A (EN)

The reversed-flow gas chromatographic technique has been applied to the determination of the apparent rate constant and the reaction order of a reaction between two gases or vapors. For seven hydrocarbons (ethane, ethene, ethyne, propene, butene, benzene and toluene) reacting with nitrogen dioxide, the above mentioned kinetic parameters have been determined. For these determinations, the necessary mathematical formulation of the problem has been written and solved, leading to simple expressions which describe the height of the chromatographic sample peaks as a function of time. (EN)

journalArticle

Rate constants (EN)
mathematics (EN)
Reaction orders (EN)
technique (EN)
hydrocarbon (EN)
gas chromatography (EN)
article (EN)
nitrogen dioxide (EN)
Gas chromatography (EN)
Reversed-flow technique (EN)
chemical reaction kinetics (EN)
priority journal (EN)
theory (EN)

Εθνικό Μετσόβιο Πολυτεχνείο (EL)
National Technical University of Athens (EN)

Chromatographia (EN)

English

1997


VIEWEG (EN)



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