Carbonyl sulfide insertion reactions into metal-alkoxide bonds. Synthesis and molecular structure of di[bis(methylthiocarbonato)tris (methanol)calcium]

 
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1995 (EN)
Carbonyl sulfide insertion reactions into metal-alkoxide bonds. Synthesis and molecular structure of di[bis(methylthiocarbonato)tris (methanol)calcium] (EN)

V. -C. Arunasalam, (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
V. -C. Arunasalam, (EN)

The reaction of COS gas with a suspension of [M(OMe)2]Ξ· (M = Mg and Ca) in methanol yields the insertion compounds, [M(OCSOMe)2(MeOH)x]Ξ· (M = Mg 1, View the MathML source) in high yield; the magnesium compound is polymeric, whilst X-ray crystallography reveals that the calcium complex 2 is a centrosymmetric dimer with eight coordinated calcium(II) ions and two distinct methylthiocarbonato (MTC) ligand coordinations modes, the structural framework being stabilised by an extensive network of hydrogen bonding. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)

1995


Elsevier (EN)



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