Coordinating Properties of 2-Acetylpyridine Thiosemicarbazone - Palladium(Ii) Complexes with Neutral and Deprotonated Ligand - X-Ray Structure of Bromo(2-Acetylpyridine Thiosemicarbazonato) Palladium(Ii)
Coordinating Properties of 2-Acetylpyridine Thiosemicarbazone - Palladium(Ii) Complexes with Neutral and Deprotonated Ligand - X-Ray Structure of Bromo(2-Acetylpyridine Thiosemicarbazonato) Palladium(Ii)
(EN)
Kovalademertzi, D.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Kovalademertzi, D.
(EN)
The preparation of the complexes PdLX, [Pd(HL)2]X2 and PdL2 (X = Cl, Br; HL and L the neutral and deprotonated ligand) is described. The new complexes have been characterized by elemental analyses, conductivity measurements and spectroscopic (IR and UV-vis) studies and the crystal and molecular structure of PdLBr has been determined by single-crystal X-ray diffraction. The palladium atom has a square planar geometry with three donor atoms (NNS) coming from L to form a planar tricyclic ligating system, and one bromide atom. All data are discussed in terms of assigned structural type and the nature of the bonding. The protonation constants of the ligand, Ka1 and Ka2, were determined by spectrophotometry and the logarithms of their values were found to be equal to 11.43 +/- 0.02 and 3.98 +/- 0.02.
(EN)
