Development of new ZSM-5 catalyst-additives in the Fluid Catalytic Cracking process for the maxinu'zation of gaseous alkenes yield

 
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2002 (EN)

Development of new ZSM-5 catalyst-additives in the Fluid Catalytic Cracking process for the maxinu'zation of gaseous alkenes yield (EN)

Lappas, A. A. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Lappas, A. A. (EN)

The catalytic activity of gallium, chromium or copper modified H-ZSM-5 zeolite as Fluid Catalytic Cracking (FCC) catalyst-additive was tested in this study. The partial ion-exchange of H-ZSM-5 with copper hindered framework dealumination upon severe steaming and resulted in significant increase of light alkenes (propylene and butylenes). The gallium and chromium impregnated H-ZSM-5 zeolites were more selective with regard to light alkenes compared to the unmodified H-ZSM-5 sample, but were not as active as the Cu-exchanged sample. An optimum balance between the number/strength of acid sites and the type/amount of in metals in the modified B-ZSM-5 catalyst-additives is required for maximization of light alkenes with relatively low gasoline loss and low coke formation. (EN)

aromatic-hydrocarbons (EN)


Impact of Zeolites and Other Porous Materials on the New Technologies at the Beginning of the New Millennium, Pts a and B (EN)

English

2002





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