A quantum mechanical study of IOX (X = Cl, Br, I) isomers

This item is provided by the institution :
University of Ioannina
Repository :
Repository of UOI Olympias
see the original item page
in the repository's web site and access all digital files if the item*

2002 (EN)
A quantum mechanical study of IOX (X = Cl, Br, I) isomers (EN)

Papayannis, D. K. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Papayannis, D. K. (EN)

Two different effective-core-potential methodologies, augmented by extra polarization functions were used to investigate a number of iodine triatomics of the type XOI, XIO and IXO (X=Cl, Br, I). The procedures were tested first on the well-studied ClOCl, BrOBr, ClOBr and IOI systems and they were shown to reproduce the full-electron calculation results with reasonable consistency. The results exhibit the same tendencies as the corresponding C1 and Br analogues and produce the greater stability for the isomer with the least electronegative atom in the middle. (C) 2002 Elsevier Science B.V. All rights reserved. (EN)

ab-initio calculations (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Chemical Physics Letters (EN)



<Go to ISI>://000177896600016

Elsevier (EN)

*Institutions are responsible for keeping their URLs functional (digital file, item page in repository site)