Gas chromatographic determination of carbonyl compounds in biological and oil samples by headspace single-drop microextraction with in-drop derivatisation

 
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2008 (EN)
Gas chromatographic determination of carbonyl compounds in biological and oil samples by headspace single-drop microextraction with in-drop derivatisation (EN)

Fiamegos, Y. C. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Fiamegos, Y. C. (EN)

A suitable method for the gas chromatographic determination of 10 characteristic carbonyls in biological and oil samples based on the in-drop formation of hydrazones by using 2,4,6-trichlorophenylhydrazine (TCPH), has been developed. The derivatisation-extraction procedure was optimized separately for aqueous and oil samples with respect to the appropriate organic drop solvent, drop volume, in-drop TCPH concentration, sample stirring rate, temperature during single-drop microextraction (SDME), reaction time and headspace-to-sample volume ratio. The optimization showed differentiation of optimum values between the studied matrices. The limits of detection were found to range from 0.001 to 0.003 mu g mL(-1) for the aqueous biological samples and from 0.06 to 0.20 mu g mL(-1) for the oil samples. The limits of quantification were in the range of 0.003-0.010 mu g mL(-1) and 0.020-0.059 mu g mL(-1) for aqueous and oil samples, respectively The overall relative standard deviations of the within-day repeatability and between-day reproducibility were < 4.4% and < 8.2% for the aqueous biological samples and < 3.9% and < 7.4% for the oxidized oil samples. (c) 2008 Elsevier B.V. All rights reserved. (EN)

headspace single-drop (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Analytica Chimica Acta (EN)

English

2008

<Go to ISI>://000253616500005

Elsevier (EN)



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