Hetero-heptanuclear (Fe-Na) complexes of salicylaldehydes: crystal and molecular structure of [Fe(2)(3-OCH(3)-salo)(8) center dot Na(5)] center dot A 3OH center dot A 8H(2)I

 
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2009 (EN)
Hetero-heptanuclear (Fe-Na) complexes of salicylaldehydes: crystal and molecular structure of [Fe(2)(3-OCH(3)-salo)(8) center dot Na(5)] center dot A 3OH center dot A 8H(2)I (EN)

Lalia-Kantouri, M. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Lalia-Kantouri, M. (EN)

The reaction of Fe(III) with the substituted salicylaldehydes [X-saloH, where X = 3-OCH(3) (L (1) ), 5-CH(3) (L (2) ), 5-Cl (L (3) ), 5-NO(2) (L (4) )] led to the formation of four new iron(III) hetero-heptanuclear complexes (Fe-Na) under the general formula [Fe(2)(X-salo)(8)Na(5)] center dot A 3OH center dot A zH(2)I. The two different coordination modes of the ligand, as well as the geometry around the metal ions were deduced by X-ray structure analysis of compound 1, [Fe(2)(3-OCH(3)-salo)(8)Na(5)] center dot A 3OH center dot A 8H(2)I. The complexes have also been characterized by physicochemical and spectroscopic (IR, UV-Vis, Mossbauer) methods. (EN)

fe(iii) (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Structural Chemistry (EN)

English

2009

<Go to ISI>://000264880400004

Springer (EN)



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