Mercuration of acetone in the acetone-mercury(II) perchlorate-2-(2'pyridyl)quinoxaline(L) system
(EN)
Garoufis, A.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Garoufis, A.
(EN)
The 1:1 reaction of HS(ClO4)(2) . 3H(2)O with 2-(2'-pyridyl) quinoxaline(L) in acetone leads to isolation of [Hg(CH2COCH3)(ClO4)L](2); the X-ray crystal structure determination together with H-1- and C-13-NMR spectra reveal the presence of the coordinated 2-oxopropyl anion. L coordinates in a bidentate, highly asymmetric mode.
(EN)
