Model studies of the interaction of vanadium(III) and oxovanadium(IV/V) with the carbonyl amide oxygen

 
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1998 (EN)
Model studies of the interaction of vanadium(III) and oxovanadium(IV/V) with the carbonyl amide oxygen (EN)

Soulti, K. D. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Soulti, K. D. (EN)

A series of vanadium(III) and oxovanadium(IV/V) compounds with the ligands, N-(2-nitrophenyl)pyridine-2-carboxamide (Hpycan), N-(phenyl)pyridine-2-carboxamide (Hpheca), and N-(2-pyridyl)acetamide (Hpyra), containing the amide functionality, was prepared and characterized both in solution and in solid state. All vanadium compounds contain a vanadium-amide oxygen bond. Crystal data for [VOCl(2)(OC(2)H(5))(Hpheca)] (4) are monoclinic; P2(1)/a; a = 12.668(5) Angstrom, b = 8.084(3) Angstrom, c = 17.222(6) Angstrom, alpha = 108.148(12)degrees; Z = 4. In addition to the synthesis and crystallographic studies, the optical, infrared, and magnetic properties of these compounds are reported. Electron paramagnetic resonance [of oxovanadium(IV) species] and (1)H, (13)C{(1)H}, and (51)V nuclear magnetic resonance [of oxovanadium(V) compounds] properties are reported as well. (EN)

protein interactions (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Inorg Chem (EN)

English

1998

<Go to ISI>://000077839100033

American Chemical Society (EN)



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