Abnormal Nucleophilic-Substitution in 3-Trichloromethylpyridine, Its N-Oxide and 3,5-Bis(Trichloromethyl)Pyridine
(EN)
Cartwright, D.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Cartwright, D.
(EN)
The scope of abnormal reactions of nucleophiles with beta-trichloromethylazines is further explored: reactions of 3-trichloromethylpyridine with nucleophiles other than methoxide, and reactions of 3-trichloromethylpyridine N-oxide and 3,5-bis(trichloromethyl)pyridine with methoxide. Attack at ;a ring carbon, followed by hydrogen migration to the side-chain, occurred in most cases, though attack at the trichloromethyl carbon was also sometimes observed.
(EN)