Abnormal Nucleophilic-Substitution in 3-Trichloromethylpyridine, Its N-Oxide and 3,5-Bis(Trichloromethyl)Pyridine

 
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1995 (EN)
Abnormal Nucleophilic-Substitution in 3-Trichloromethylpyridine, Its N-Oxide and 3,5-Bis(Trichloromethyl)Pyridine (EN)

Cartwright, D. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Cartwright, D. (EN)

The scope of abnormal reactions of nucleophiles with beta-trichloromethylazines is further explored: reactions of 3-trichloromethylpyridine with nucleophiles other than methoxide, and reactions of 3-trichloromethylpyridine N-oxide and 3,5-bis(trichloromethyl)pyridine with methoxide. Attack at ;a ring carbon, followed by hydrogen migration to the side-chain, occurred in most cases, though attack at the trichloromethyl carbon was also sometimes observed. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Tetrahedron (EN)

English

1995

<Go to ISI>://A1995TE49500001

Elsevier (EN)



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