Novel vanadium(III/IV) compounds with the diamidate ligand 1,2-bis(2-pyridinecarboxamide)benzene (H(2)bpb)

 
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Novel vanadium(III/IV) compounds with the diamidate ligand 1,2-bis(2-pyridinecarboxamide)benzene (H(2)bpb) (EN)

Vlahos, A. T. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Vlahos, A. T. (EN)

Reaction of the diamidate ligand H(2)bpb with VCl3 depending on the base affords either the compound NHEt(3){trans-[(VCl2)-Cl-III(bpb)]} 1 or [V-III(Hbpb)(3)]. 2CHCl(3) 2; aerial oxidation-hydrolysis of 1 gives the dimeric species [VOCl(Hbpb)](2) . 2MeNO(2) 3; the X-ray-crystal structures of 1, 2 and 3 are reported. (EN)

complexes (EN)


Chemical Communications (EN)

English

1997


Royal Society of Chemistry (EN)



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