Oxamate and chloranilate bridges in polymeric networks

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University of Ioannina
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1997 (EN)
Oxamate and chloranilate bridges in polymeric networks (EN)

Veltsistas, P. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Veltsistas, P. (EN)

Oxamic acid acts as a bridging ligand with lanthanide ions to form, for example 9-coordinate Ho(III) systems in which the holmium centres are linked into sheets via H-bonds. Nd(III) also forms 9-coordinate complexes with oxamate but an alternative packing motif is observed. Multidentate ligands such as chloroanilate can also induce interesting networks. Thus with sodium and phenanthroline a complex which contains 7-coordinate sodium atoms linked together to form infinite double chains is observed. (EN)

supramolecular structures (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Phosphorus Sulfur and Silicon and the Related Elements (EN)



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