[Pr(NO3)(3)L]: a mononuclear ten-coordinate lanthanide(III) complex with a tetradentate di-Schiff base

 
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[Pr(NO3)(3)L]: a mononuclear ten-coordinate lanthanide(III) complex with a tetradentate di-Schiff base (EN)

Gourbatsis, S. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Gourbatsis, S. (EN)

The novel praseodymium(III) complex [Pr(NO3)(3)L] (1), where L=N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine, has been obtained by direct reaction of the Schiff base and the metal salt; the gadolinium(III) homologue has also been prepared and so far characterized only spectroscopically. The crystal structure resembles those reported for hexadentate macrocyclic Schiff bases. (C) 1999 Elsevier Science S.A. All rights reserved. (EN)

crystal structures (EN)


Inorganic Chemistry Communications (EN)

English

1999


Elsevier (EN)



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