Preparation and Characterization of [Cu2cl4l2] - the 1st Structural Determination of a Complex Containing the Novel Ligand 2-(2'-Pyridyl)Quinoxaline (L)

 
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1993 (EN)
Preparation and Characterization of [Cu2cl4l2] - the 1st Structural Determination of a Complex Containing the Novel Ligand 2-(2'-Pyridyl)Quinoxaline (L) (EN)

Plakatouras, J. C. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Plakatouras, J. C. (EN)

The reaction of the unexpectedly formed ligand 2-(2'-pyridyl)quinoxaline (L) With CuCl2 in ethanol, followed by recrystallization from methanol, yields the dinuclear copper (II) complex [Cu2Cl4L2]. The crystal structure of this compound shows a bidentate chelating behaviour of L and different (terminal, asymmetric bridging) chloride coordination modes. Some properties of the dimer are also described. (EN)

magnetic characterization (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)

English

1993

<Go to ISI>://A1993LX69000019

Pergamon Press Ltd. (EN)



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