Preparation and Characterization of [Cu2cl4l2] - the 1st Structural Determination of a Complex Containing the Novel Ligand 2-(2'-Pyridyl)Quinoxaline (L)
Preparation and Characterization of [Cu2cl4l2] - the 1st Structural Determination of a Complex Containing the Novel Ligand 2-(2'-Pyridyl)Quinoxaline (L)
(EN)
Plakatouras, J. C.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Plakatouras, J. C.
(EN)
The reaction of the unexpectedly formed ligand 2-(2'-pyridyl)quinoxaline (L) With CuCl2 in ethanol, followed by recrystallization from methanol, yields the dinuclear copper (II) complex [Cu2Cl4L2]. The crystal structure of this compound shows a bidentate chelating behaviour of L and different (terminal, asymmetric bridging) chloride coordination modes. Some properties of the dimer are also described.
(EN)
