Preparation and spectral studies of dinuclearmixed-ligand copper(I) complexes. The crystal structure of bis[ΞΌ-S(Pyridine-2-Thione)(tmtp) Copper(I)Bromide] (EN)

Aslanidis, P. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)

Aslanidis, P. (EN)

[Cu(tmtp)Br]n (tmtp = tri-m-tolylphosphine) reacts with heterocyclic thiones (L) [L = pyridine-2-thione (py2SH), 1,3-thiazolidine-2-thione (tzdtH), benz-1,3-imidazoline-2-thione (bzimtH2), benz-1,3-thiazoline-2-thione (bztzdtH), imidazoline-2-thione (imtH), benz-1,3-oxazoline-2-thione (bzoxtH2), 5-nitrobenz-1,3-imidazoline-2-thione (nbzimtH2), and 5-methyl-benz-1,3-imidazoline-2-thione (mebzimtH2)] to give binuclear complexes of the general formula [Cu(tmtp)(L)Br]2. These complexes have been characterized by various spectroscopic methods. The crystal structure of the pyridine-2-thione complex has been determined by single-crystal X-ray diffraction methods. The molecule contains a planar Cu2S2 moiety with Cuξ—ΈS bond lengths of 2.3348(9) and 2.4879(7) Γ…. The Cuξ—ΈBr and Cuξ—ΈP distances are 2.4929(1) and 2.2525(4) Γ…, respectively, whereas the Cuβ‹―Cu separation is 2.6906(1) Γ…. (EN)

Πανεπιστήμιο Ιωαννίνων

Ιδρυματικό Αποθετήριο Ολυμπιάς

Σχολή Θετικών Επιστημών

Άρθρα σε επιστημονικά περιοδικά ( Ανοικτά)

ΑΠΟΘΕΤΗΡΙΟ "ΟΛΥΜΠΙΑΣ"

Τμήμα Χημείας

Polyhedron (EN)

Αγγλική γλώσσα

1994

http://olympias.lib.uoi.gr/jspui/handle/123456789/8923

http://www.sciencedirect.com/science/article/pii/S0277538700836803

Elsevier (EN)