Preparation, Properties, and Structural Characterization of 2-oxathioamidate Complexes

 
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1994 (EN)
Preparation, Properties, and Structural Characterization of 2-oxathioamidate Complexes (EN)

M. L. B. F. Hereygers, (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
M. L. B. F. Hereygers, (EN)

The reactions of potassium 2-thiooxamate (K+HL�) and potassium N-methyl-2-thiooxamate (K+HA�) with divalent metal ions yield a variety of products. The anions HL� and HA� behave as O,S bidentate chelating ligands, while L2� and A2� act as O,N/O,S bis-bidentate bridging ligands yielding polymeric complexes. The crystal structures oftrans-[Mn(HL)2(H2O)2],trans-[Cd(HL)2(H2O2] andcis-[Mn(HA)2(H2O)2]·H2O have been solved. Some properties of the complexes prepared are also described. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)

English

1994


Elsevier (EN)



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