Reaction of C-60 with Dimethyldioxirane - Formation of an Epoxide and a 1,3-Dioxolane Derivative

 
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1992 (EN)
Reaction of C-60 with Dimethyldioxirane - Formation of an Epoxide and a 1,3-Dioxolane Derivative (EN)

Elemes, Y. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Elemes, Y. (EN)

Not an oxygen-bridged annulene (structural type 1) but rather an epoxide (structural type 2) is the product of the reaction of dimethyldioxirane with C60. In a competing reaction, a 1,3-dioxolane (structural type 3) is formed-probably by a diradical mechanism. Cleavage of acetone from 3 leading to 2 was not observed at temperatures up to 110-degrees-C. Compound 3 could provide access to ring-opened fullerenes. (EN)

all-carbon molecules (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Angewandte Chemie-International Edition in English (EN)

English

1992

<Go to ISI>://A1992HX98600035



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