Reactivity of di-iodine toward thiol: Desulfuration reaction of 5-nitro-2-mercaptobenzimidazole upon reaction with di-iodine

 
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2012 (EN)
Reactivity of di-iodine toward thiol: Desulfuration reaction of 5-nitro-2-mercaptobenzimidazole upon reaction with di-iodine (EN)

G.J. Corban, (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
G.J. Corban, (EN)

The reaction of 2-mercapto-benzoic acid (H2MBA), 2-mercato-nicotinic acid (H2MNA), and 2-mercapto-pyrimidine (PMTH) with a twofold molar amount of di-iodine (I2) results in the isolation of crystals of the neutral disulfides of formulae: {(HMBA)2Β·1/2(CH3CN)} (1), {(HMNA)2Β·(H2O)} (2), and (PMT)2 (3), respectively, when dichloromethane/acetonitrile/methanol (1) or dichloromethane (2,3) were used as solvents. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Heteroatom Chemistry (EN)

English

2012


Wiley (EN)



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