Rh-II-catalyzed thermal cyclopropanations of a phenyliodonium bis(carbomethoxy)methylide with alkenes and dienes

 
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Rh-II-catalyzed thermal cyclopropanations of a phenyliodonium bis(carbomethoxy)methylide with alkenes and dienes (EN)

Georgakopoulou, G. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Georgakopoulou, G. (EN)

Iodonium ylide 2, derived from dimethyl malonate, undergoes facile thermal cycloaddition with alkenes and dienes catalyzed with Rh-2(OAc)(4) to form the corresponding cyclopropanedicarboxylates and vinylcyclopropanedicarboxylates, respectively, in excellent yields. (EN)

hypervalent iodine (EN)


Synlett (EN)

English

2001




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