Solution and structural studies of the Cd(II) - Aconitate system

 
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2009 (EN)
Solution and structural studies of the Cd(II) - Aconitate system (EN)

Kostakis, G. E. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Kostakis, G. E. (EN)

The complexing ability of the binary system trans-aconitic acid (H(3)L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H(3)L), [Cd(3)L(2)(H(2)O)(6)] n(1) and ternary systems of Cd(II)-(H(3)L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved. (EN)

potentiometry (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)

English

2009

<Go to ISI>://000271144200010

Elsevier (EN)



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