Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-)

 
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2008 (EN)
Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-) (EN)

Miras, H. N. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Miras, H. N. (EN)

A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, [Mo(11)(VI)V(5)(V)V(2)(IV)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry. (EN)

building-blocks (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Chemical Communications (EN)

English

2008

<Go to ISI>://000259678200006

Royal Society of Chemistry (EN)



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