Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-)
Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: [Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-)
(EN)
Miras, H. N.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Miras, H. N.
(EN)
A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, [Mo(11)(VI)V(5)(V)V(2)(IV)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry.
(EN)
