Sulfur Dioxide Insertion Reactions Into Metal Alkoxide Bonds: Synthesis and Crystal Structure of catena-Bis(methylsulfito)bis(methanol)calcium; a One-dimensional Polymer Based on Eight-Coordinate Calcium Ions

 
This item is provided by the institution :
University of Ioannina
Repository :
Repository of UOI Olympias
see the original item page
in the repository's web site and access all digital files if the item*
share



1994 (EN)
Sulfur Dioxide Insertion Reactions Into Metal Alkoxide Bonds: Synthesis and Crystal Structure of catena-Bis(methylsulfito)bis(methanol)calcium; a One-dimensional Polymer Based on Eight-Coordinate Calcium Ions (EN)

V. -C. Arunasalam, (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
V. -C. Arunasalam, (EN)

The reaction of So2(g) with a suspension of [M(OMe)2]n(M = Mg and Ca) in methanol yields the crystalline compounds, [M(O2SOMe)2(MeOH)2]�(M = Mg 1, Ca 2); the insertion reaction is of high yield and the X-ray crystal structure of complex 2 reveals that it is a chain polymer with eight-coordinated CaII ions and the methylsulfito anions acting as both chelating and bridging ligands. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

J. Chem. Soc., Chem. Commun. (EN)

English

1994


Royal Society of Chemistry (EN)



*Institutions are responsible for keeping their URLs functional (digital file, item page in repository site)