Supramolecular assemblies involving metal-organic ring interactions: heterometallic Cu(II)-Ln(III) two-dimensional coordination polymers

 
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2012 (EN)

Supramolecular assemblies involving metal-organic ring interactions: heterometallic Cu(II)-Ln(III) two-dimensional coordination polymers (EN)

Konidaris, K. F. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Konidaris, K. F. (EN)

Three isostructural two-dimensional coordination polymers of the general formula [Ln(2)(CuL)(3)(H2O)(9)]center dot 5.5H(2)O, where Ln = La (1), Nd (2), and Gd (3), have been synthesized and isolated from aqueous solutions and their single-crystal structures determined by X-ray diffraction. The supramolecular interaction between the non-aromatic metallorings plays an important role in stabilizing the structure of these compounds. The thermal stability, reversible solvent uptake, electronic properties and magnetic studies of these compounds are also reported. (EN)

magnetic-properties (EN)


Crystengcomm (EN)

English

2012


The Royal Society of Chemistry (EN)




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