Synthesis and reactions of 1-aryl-2-nitropyrroles. Structural and conformational study of ethyl N-[2'-[1'-(2-nitropyrrolyl)]phenyl]-N-toluene-4-sulfonamide glycinate

 
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1996 (EN)
Synthesis and reactions of 1-aryl-2-nitropyrroles. Structural and conformational study of ethyl N-[2'-[1'-(2-nitropyrrolyl)]phenyl]-N-toluene-4-sulfonamide glycinate (EN)

Cobb, J. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Cobb, J. (EN)

Nitration of 1-aryl(or 1-benzyl)pyrroles 1, 2 and 7 has provided the corresponding 2- and 3-nitropyrroles 3 and 5, 4 and 6, and 8 and 9 in a 1:2 ratio. Reductive cyclisation of 3 and 8, gave pyrrolo[1,2-a]quinazolines 11 and 12. and pyrrolo[1,2-b][2,4]benzodiazepine 13. respectively. A conformational study of 5 in the solid and Liquid state using X-ray diffraction analysis. molecular dynamics calculations and NMR spectroscopy is described. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Tetrahedron (EN)

English

1996

<Go to ISI>://A1996UA51000029

Elsevier (EN)



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