Synthesis and Spectroscopic Characterization of the Heterobimetallic Chain Compounds [Mpdl2]N and [Cuptl2]N (M = Co, Ni, Cu, Zn, Pt - L2- = N,N'-Dimethylmonothiooxamido)

 
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1993 (EN)
Synthesis and Spectroscopic Characterization of the Heterobimetallic Chain Compounds [Mpdl2]N and [Cuptl2]N (M = Co, Ni, Cu, Zn, Pt - L2- = N,N'-Dimethylmonothiooxamido) (EN)

Perlepes, S. P. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Perlepes, S. P. (EN)

By using the ''complexes as ligands'' synthetic strategy and the unique [Pd(LH)2] and [Pt(LH)2] precursors, the novel heterobimetallic polymeric compounds [MPdL2]n and [CuPtL2]n (M = Co, Ni, Cu, Zn, Pt; L2- = the dianion of N,N'-dimethylmonothiooxamide) have been prepared. The vibrational analysis of the complexes is given using various isotopic substitutions. The polymers consist of alternate planar PdO2S2 (or PtO2S2) and tetrahedrally-distorted planar MN4 structural units. (EN)

monothiooxamides (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Spectroscopy Letters (EN)

English

1993

<Go to ISI>://A1993LD54700005

Taylor & Francis (EN)



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