Synthesis and X-Ray Structures of Bis(3,5-Di-Tert-Butylcatecholato)(Phenanthroline)Vanadium(Iv) and Its Vanadium(V) Analog [V(Dtbc)2(Phen)][Sbf6]
(EN)
Kabanos, T. A.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Kabanos, T. A.
(EN)
Bis(3,5-di-tert-butylcatecholato)(phenanthroline)vanadium(iv) 1 is prepared, and oxidised with silver hexafluoroantimonate to give its vanadium(v) analogue 2; both complexes are characterised by X-ray crystallography revealing significant differences in their coordination geometry.
(EN)