Synthesis of novel 3,4-dihydro-2H-pyrrolo[60]fullerene derivatives bearing an alkylsulfanyl substituent

 
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2004 (EN)
Synthesis of novel 3,4-dihydro-2H-pyrrolo[60]fullerene derivatives bearing an alkylsulfanyl substituent (EN)

Naxakis, G. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Naxakis, G. (EN)

C-60 reacts thermally with azomethine ylides of glycine imines, in methyl ester and free acid form, bearing two alkylsulfanyl groups to give dihydro-pyrrolo[60]fullerene derivatives 2 and 5a, respectively, in a 1,3-dipolar cycloaddition reaction. The yields of products were found to depend strongly on acidic conditions applied and the size of the alkylsulfanyl substituent. Graphics. a: R=Me, b: R=Et, a R=Pro, d: R=i-Pro. (EN)

fullerenes (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Fullerenes Nanotubes and Carbon Nanostructures (EN)

English

2004

<Go to ISI>://000225614900006

Taylor & Francis (EN)



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