Synthesis, and Structural Characterization, of Two Novel, CdIII Ξ²-diketonates [Gd4(ΞΌ3-OH)4(ΞΌ2-H2O)2(H2O)4(hfpd)8].2C6H6.H2O (1) and [Gd(hfpd)3(MeCO)(H2O)] (2) (hfpd-H: 1,1,1,5,5,5-hexafluoropentane-2,4-dione)

 
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1994 (EN)
Synthesis, and Structural Characterization, of Two Novel, CdIII Ξ²-diketonates [Gd4(ΞΌ3-OH)4(ΞΌ2-H2O)2(H2O)4(hfpd)8].2C6H6.H2O (1) and [Gd(hfpd)3(MeCO)(H2O)] (2) (hfpd-H: 1,1,1,5,5,5-hexafluoropentane-2,4-dione) (EN)

J. C. Plakatouras, (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
J. C. Plakatouras, (EN)

Two novel Gdlll-hfpd complexes 1 and 2 have been synthesised from aqueous and non-aqueous media; the crystal structural studies reveal that 1 has a M406 bicapped cubane core with the metals having tricapped trigonal prismatic geometry, while 2 is a monomeric adduct with water and acetone in the coordination sphere, with the metal having square antiprismatic geometry. (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

J. Chem. Soc., Chem. Commun. (EN)

English

1994




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