Synthesis, and Structural Characterization, of Two Novel, CdIII Ξ²-diketonates [Gd4(ΞΌ3-OH)4(ΞΌ2-H2O)2(H2O)4(hfpd)8].2C6H6.H2O (1) and [Gd(hfpd)3(MeCO)(H2O)] (2) (hfpd-H: 1,1,1,5,5,5-hexafluoropentane-2,4-dione)
Synthesis, and Structural Characterization, of Two Novel, CdIII Ξ²-diketonates [Gd4(ΞΌ3-OH)4(ΞΌ2-H2O)2(H2O)4(hfpd)8].2C6H6.H2O (1) and [Gd(hfpd)3(MeCO)(H2O)] (2) (hfpd-H: 1,1,1,5,5,5-hexafluoropentane-2,4-dione)
(EN)
J. C. Plakatouras,
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
J. C. Plakatouras,
(EN)
Two novel Gdlll-hfpd complexes 1 and 2 have been synthesised from aqueous and non-aqueous media; the crystal structural studies reveal that 1 has a M406 bicapped cubane core with the metals having tricapped trigonal prismatic geometry, while 2 is a monomeric adduct with water and acetone in the coordination sphere, with the metal having square antiprismatic geometry.
(EN)
