Synthesis, characterization and X-ray structural determination of the nine-coordinate tris-aqua tetra-oxamato neodymium(III) complex [Nd(Hoxm)(3)(H(2)oxm) center dot 2.5H(2)O](n)
Synthesis, characterization and X-ray structural determination of the nine-coordinate tris-aqua tetra-oxamato neodymium(III) complex [Nd(Hoxm)(3)(H(2)oxm) center dot 2.5H(2)O](n)
(EN)
Veltsistas, P. G.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Veltsistas, P. G.
(EN)
The reaction of Nd-III with oxamic acid yields [Nd(Hoxm)(3)(H(2)oxm). 2.5H(2)O](n) 1 (H(2)oxm = oxamic acid) which contains nine-coordinate Nd centres linked into chains via four-coordinate Hoxm(-) ligands; the chains are connected via an array of H-bonds.
(EN)