Synthesis, solution and spectral studies of palladium(II) complexes with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone. Crystal structure of a tripalladium complex
Synthesis, solution and spectral studies of palladium(II) complexes with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone. Crystal structure of a tripalladium complex
(EN)
Yadav, P. N.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Yadav, P. N.
(EN)
The reactions of palladium(II) salts with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone, H(2)Ap3Pr, are described. The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion, Ap3Pr(2-), are reported. The X-ray crystal structure determination of [Pd(Ap3Pr(2))](3).DMF shows it to contain a chair-form hexagon of alternating Pd and S atoms to form a molecular bowl. The spectrophotometric characterization of H(2)Ap3Pr is also reported. (C) 2002 Elsevier Science B.V. All rights reserved.
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