Synthesis, solution and spectral studies of palladium(II) complexes with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone. Crystal structure of a tripalladium complex

 
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2002 (EN)

Synthesis, solution and spectral studies of palladium(II) complexes with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone. Crystal structure of a tripalladium complex (EN)

Yadav, P. N. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Yadav, P. N. (EN)

The reactions of palladium(II) salts with 2-hydroxyacetophenone N(3)-propylthiosemicarbazone, H(2)Ap3Pr, are described. The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion, Ap3Pr(2-), are reported. The X-ray crystal structure determination of [Pd(Ap3Pr(2))](3).DMF shows it to contain a chair-form hexagon of alternating Pd and S atoms to form a molecular bowl. The spectrophotometric characterization of H(2)Ap3Pr is also reported. (C) 2002 Elsevier Science B.V. All rights reserved. (EN)

trinuclear triangulo palladium (ii) (EN)


Inorganica Chimica Acta (EN)

English

2002





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