Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H(2)O)]center dot 3(H(2)O)}2 (H(3)L = trans-aconitic acid)

 
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Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H(2)O)]center dot 3(H(2)O)}2 (H(3)L = trans-aconitic acid) (EN)

Kostakis, G. E. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Kostakis, G. E. (EN)

The reaction of Zn(NO(3))(2)center dot 3(H(2)O) with trans-aconitic acid (H(3)L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H(2)O)]center dot 3(H(2)O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved. (EN)

hexameric water cluster (EN)


Inorganic Chemistry Communications (EN)

English

2011


Elsevier (EN)



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