Tele vs. oxidative substitution of hydrogen in meta monochloromethyl, dichloromethyl, and trichloromethyl nitrobenzenes in the reaction with Grignard reagents
Tele vs. oxidative substitution of hydrogen in meta monochloromethyl, dichloromethyl, and trichloromethyl nitrobenzenes in the reaction with Grignard reagents
(EN)
Makosza, M.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Makosza, M.
(EN)
Grignard reagents add to nitrobenzene derivatives containing trichloromethyl, dichloromethyl, and monochloromethyl groups in the meta position to form sigma(H) adducts, which are either further converted through departure of a chloride anion, giving products of tele substitution, or oxidized to products of oxidative nucleophilic substitution of hydrogen. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).
(EN)
