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1991 (EN)

The Ferrocenylmethyl Radical (EN)

Jackson, R. A. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Jackson, R. A. (EN)

Ferrocenylmethyl, dideuterio(ferrocenyl)methyl and 1'-methylferrocenylmethyl radicals have been prepared by gamma-irradiation of the parent ferrocene derivatives in adamantane matrices. Ferrocenylmethyl shows a triplet splitting (14.7 G) in its EPR spectrum attributed to the two alpha-protons; the couplings from the ring protons are buried in the linewidth. The high g value of 2.0200 indicates involvement of the Fe orbitals in the delocalized radical. (EN)


Journal of the Chemical Society-Perkin Transactions 2 (EN)

English

1991


Royal Society of Chemistry (EN)




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