Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Jackson, R. A.
(EN)
Ferrocenylmethyl, dideuterio(ferrocenyl)methyl and 1'-methylferrocenylmethyl radicals have been prepared by gamma-irradiation of the parent ferrocene derivatives in adamantane matrices. Ferrocenylmethyl shows a triplet splitting (14.7 G) in its EPR spectrum attributed to the two alpha-protons; the couplings from the ring protons are buried in the linewidth. The high g value of 2.0200 indicates involvement of the Fe orbitals in the delocalized radical.
(EN)