The first experimental evidence of differential hydration of E/Z isomers of sterically hindered amides: One dimensional steady-state selective intermolecular C-13, H-1 overhauser effect study of tert-butylformamide

 
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1996 (EN)
The first experimental evidence of differential hydration of E/Z isomers of sterically hindered amides: One dimensional steady-state selective intermolecular C-13, H-1 overhauser effect study of tert-butylformamide (EN)

Gerothanassis, I. P. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Gerothanassis, I. P. (EN)

One dimensional steady-state selective intermolecular C-13, H-1 Overhauser effect study of tert-butylformamide provides the first experimental evidence of differentical hydration of the Z isomer, compared to the E isomer, due to the presence of the bulky tert-butyl group; the significant decrease in the population of the Z isomer should be attributed to steric effects and deformation of the amide bond with hydration differences playing a significant role. Copyright (C) 1996 Elsevier Science Ltd (EN)

nuclear-magnetic-resonance (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Tetrahedron Lett (EN)

English

1996

<Go to ISI>://A1996VE83100039

Elsevier (EN)



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