The preparation and X-ray structure of [M{(SePPh2)(2)N}(2)], M=Ni, Pd, Pt

 
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1997 (EN)
The preparation and X-ray structure of [M{(SePPh2)(2)N}(2)], M=Ni, Pd, Pt (EN)

Papadimitriou, C. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Papadimitriou, C. (EN)

Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd. (EN)

platinum (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)

English

1997

<Go to ISI>://A1997XC47600004



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