The preparation and X-ray structure of [M{(SePPh2)(2)N}(2)], M=Ni, Pd, Pt

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1997 (EN)
The preparation and X-ray structure of [M{(SePPh2)(2)N}(2)], M=Ni, Pd, Pt (EN)

Papadimitriou, C. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Papadimitriou, C. (EN)

Reaction of [Ni(CH3CO)(2)]4H(2)O, H2PdCl4 or H2PtCl6 with HN[P(Se)Ph-2](2) in water/acetone gave the title compounds in good yield. The compounds were characterised by IR/Raman, NMR and X-ray crystallography. The square planar metal centres form parts of spiro pseudo-boat rings. The X-ray structures allow comparison of the radii of Pt and Pd atoms. (C) 1997 Elsevier Science Ltd. (EN)

platinum (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)



<Go to ISI>://A1997XC47600004

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