Approaches to Molecular Magnetic Materials from the Use of Cyanate Groups in Higher Oxidation State Metal Cluster Chemistry: Mn14 and Mn16

 
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2013 (EN)
Approaches to Molecular Magnetic Materials from the Use of Cyanate Groups in Higher Oxidation State Metal Cluster Chemistry: Mn14 and Mn16 (EN)

Alexandropoulos, D. I. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Alexandropoulos, D. I. (EN)

The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem-diolate form of di-2-pyridylketone or 2,6-diacetylpyridine dioxime chelate ligands, has afforded structurally interesting MnII/III14 and MnII/III/IV16 clusters, respectively. In both complexes, the end-on bridging cyanato groups show an obvious preference in binding through their O atom, a significantly different ligation than that for the homoatomic-type N3 ligand. The Mn14 compound shows entirely visible out-of-phase signals below 5 K and large hysteresis loops below 2 K. (EN)

cluster compounds (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

European Journal of Inorganic Chemistry (EN)

English

2013

<Go to ISI>://000318167500002

Wiley-VCH Verlag (EN)



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