Assembly of a helical zinc(II) chain and a two-dimensional cadmium(II) coordination polymer using picolinate and sulfate anions as bridging ligands

 
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2007 (EN)
Assembly of a helical zinc(II) chain and a two-dimensional cadmium(II) coordination polymer using picolinate and sulfate anions as bridging ligands (EN)

Papatriantafyllopoulou, C. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Papatriantafyllopoulou, C. (EN)

The initial use of the picolinate (pic(-))/sulfate "blend" in metal chemistry has yielded two neutral coordination polymers. Complexes [Zn-2(SO4)(pic)(2)(H2O)(3)](n) (1) and [Cd-2(SO4)(pic)(2)(H2O)(3)](n) center dot nH(2)O (2 center dot nH(2)O) were prepared by the reaction of MSO4 center dot xH(2)O [M = Zn, x = 7; M = Cd, x = 8/3] with one equivalent of picolinic acid (picH) in aqueous solution in the absence of external base. The structures of both compounds have been determined by single-crystal X-ray crystallography. Complex I consists of helical chains which interact through hydrogen bonds and stacking interactions to form a 3D, 5-connected network. Complex 2 - nH(2)O consists of ribbons that are crosslinked by the sulfato ligands to give a 2D, 4-connected network. Hydrogen bonds and stacking interactions lead to the formation of a 3D supramolecular architecture. In both coordination complexes, the pic ligand adopts two different bridging coordination modes (2.111 and 2.201 in 1; 2.211 and 2.201 in 2 center dot nH(2)O), while the SO42- behaves as a bidentate bridging 2.1100 (Harris notation) ligand. The Zn(II) complex has 5- and 6-coordinate metal ions, whereas 6- and 7-coordinate Cd-11 atoms are present in 2 - nH(2)O. Characteristic vibrational (IR, Raman) bands are discussed in terms of the known structures, and the coordination modes of the pic(-) and SO42- ligands. The thermal decomposition of the Cd(11) compound has also been studied. (C) 2007 Elsevier Ltd. All rights reserved. (EN)

cadmium(ii) sulfato complexes (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Polyhedron (EN)

English

2007

<Go to ISI>://000249905900004

Elsevier (EN)



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