A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

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Title

A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins (EN)

Creator

Daphnomili, D. (EN)

Contributor

Daphnomili, D. (EN)

Issued

2010

Year

2010 (EN)

Description

The synthesis of new trans A(2)B(2)-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by (1)H-N.M.R., (13)C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined. (EN)

Scientific field

Natural Sciences
Chemical sciences (EN)

Subject

dipyrromethanes (EN)

Journal

Bioinorg Chem Appl (EN)

Language

English

Publisher

Hindawi Publishing Corporation (EN)

School / Department / Institute

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)