New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigation

 
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New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigation (EN)

Sofas, G. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Sofas, G. (EN)

A new Nickel complex with an extended multisulfur dithiolene ligand Ni(edodddt)(2) (edodddt = 2,3,4 alpha,8 alpha-tetrahydro-dithiine [2,3-b] [1,4] dioxo-6,7-dithiolene) has been synthesized and characterized by electrochemical measurements, IR, UV-Vis and NMR spectroscopy. Its crystal structure was resolved by X-ray diffraction on a single crystal. DFT calculations were made in order to compare the results with the experimental findings and gain an insight of the properties of this new dithiolene complex. (c) 2009 Elsevier Ltd. All rights reserved. (EN)

dithiolene complexes (EN)


Polyhedron (EN)

English

2009


Elsevier (EN)



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