Assembly of a porous three-dimensional coordination polymer: Crystal structure of {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n)
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Kiritsis, V.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
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Kiritsis, V.
(EN)
The structure and dehydration behavior of the porous 3D coordination polymer {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n) are described. Each La3+ is coordinated by nine oxygen atoms belonging to five carboxylate ligands and to two water molecules. Large infinite interconnected channels filled with hydrogen-bonded water molecules are formed in the structure. Upon heating, this compound transforms reversibly into a nonporous lower hydrate.
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