Assembly of a porous three-dimensional coordination polymer: Crystal structure of {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n)

 
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1998 (EN)
Assembly of a porous three-dimensional coordination polymer: Crystal structure of {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n) (EN)

Kiritsis, V. (EN)

Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας (EL)
Kiritsis, V. (EN)

The structure and dehydration behavior of the porous 3D coordination polymer {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n) are described. Each La3+ is coordinated by nine oxygen atoms belonging to five carboxylate ligands and to two water molecules. Large infinite interconnected channels filled with hydrogen-bonded water molecules are formed in the structure. Upon heating, this compound transforms reversibly into a nonporous lower hydrate. (EN)

metal-organic framework (EN)

Πανεπιστήμιο Ιωαννίνων (EL)
University of Ioannina (EN)

Inorg Chem (EN)

English

1998

<Go to ISI>://000074579300039

American Chemical Society (EN)



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