Bis(sulfonyl)methyl insertion into alkenyl versus phenyl carbon-hydrogen bonds in the reaction of bis(sulfonyl)iodonium ylides with highly phenylated ethylenes
Bis(sulfonyl)methyl insertion into alkenyl versus phenyl carbon-hydrogen bonds in the reaction of bis(sulfonyl)iodonium ylides with highly phenylated ethylenes
(EN)
Adam, W.
(EN)
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας
(EL)
Adam, W.
(EN)
The reaction of bis(sulfonyl)iodonium ylides alpha-gamma with triphenylethylene (2a) and tetraphenylethylene (2b) affords insertion products into the alkenyl and phenyl carbon-hydrogen bonds of the substrate. A mechanistically perplexing feature is the diversity displayed in the reactivity pattern of the bis(sulfonyl)iodonium ylides in their reaction with the phenylated alkenes.
(EN)
