Bis[1,2-diphenyl-1,2-ethylenedithiolato(2-)-kS(1),kS(2)] gold: Preparation, structure and properties

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Bis[1,2-diphenyl-1,2-ethylenedithiolato(2-)-kS(1),kS(2)] gold: Preparation, structure and properties

Raptopoulou, Catherine P.
Petrouleas, Vassilis
Παπαβασιλείου Γεώργιος
Ioannidis, Nikos
Psycharis, Vassilis
Anyfantis, George C.
Paraskevopoulou, Patrina

Άρθρο σε επιστημονικό περιοδικό

2009-10-13


Starting from 4,5-diphenyl-1,3-dithiol-2-one, the title complex was prepared and studied. Single crystal X-ray structure determination showed that the complex crystallized in the triclinic system, space group P (1) over bar. It is isostructural with the beta-form of the nickel analogue and the molecules have a dissymmetric structure. Structural and EPR data were found to be close to the theoretically calculated ones. Optical and electrochemical data indicate that the complex is stable in air and could be a candidate material for fabrication of electronic devices.
Oxford

Κρυσταλλογραφία (EL)
Χημεία (Γενικά) (EL)
Chemistry (General) (EN)
Crystallography (EN)

Chemistry, Inorganic & Nuclear
Metal 1,2-dithiolenes
Optical properties
Redox properties
EPR spectra
Crystal structure

English

Pergamon-elsevier Science Limited


Polyhedron (incorporating Inorganic and Nuclear Chemistry Letters and Journal of Inorganic and Nuclear Chemistry)

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© 2009 Elsevier Ltd. All rights reserved.
© 2009 Elsevier Ltd. All rights reserved. (EN)




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