A combined synchrotron powder diffraction and vibrational study of the thermal treatment of palygorskite-indigo to produce Maya blue

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A combined synchrotron powder diffraction and vibrational study of the thermal treatment of palygorskite-indigo to produce Maya blue

van Beek, Wouter
Tsiantos, Constantinos
Suarez, Mercedes
Γκιώνης, Βασίλης
Boccaleri, Enrico
Milanesio, Marco
Χρυσικός, Γεώργιος Δ.
Sanchez del Rio, Manuel
Garcia-Romero, Emilia
Croce, Gianluca
Kacandes, George H.

Άρθρο σε επιστημονικό περιοδικό

2009-10


NEW YORK
The heating process (30-200 A degrees C) of a palygorskite-indigo mixture has been monitored in situ and simultaneously by synchrotron powder diffraction and Raman spectroscopy. During this process, the dye and the clay interact to form Maya blue (MB), a pigment highly resistant to degradation. It is shown that the formation of a very stable pigment occurs in the 70-130 A degrees C interval; i.e., when palygorskite starts to loose zeolitic water, and is accompanied by a reduction of the crystallographic a parameter, as well as by alterations in the C=C and C=O bonds of indigo. Mid- and near-infrared spectroscopic work and microporosity measurements, employed to study the rehydration process after the complex formation, provide evidence for the inhibition of the rehydration of MB as compared with palygorskite. These results are consistent with the blocking of the palygorskite tunnel entrance by indigo molecules with a possible partial penetration inside the tunnels. The surface silanols of palygorskite are not perturbed by indigo, suggesting that MB is not a surface complex.

Επιστήμη (Γενικά) (EL)
Τεχνολογία (Γενικά) (EL)
Technology (General) (EN)
Science (General) (EN)

Materials Science, Multidisciplinary

Αγγλική γλώσσα

Springer New York LLC


Journal of Materials Science (incorporating Journal of Materials Science: Letters and Interface Science)

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© SPRINGER (EN)




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