Pulsed-field gradient nuclear magnetic resonance study of transport properties of fluid catalytic cracking catalysts

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Pulsed-field gradient nuclear magnetic resonance study of transport properties of fluid catalytic cracking catalysts (EN)

Papadopoulos, GK (EN)
Stocker, M (EN)
McElhiney, G (EN)
Berger, C (EN)
Perez, M (EN)
Weitkamp, J (EN)
Elia, MF (EN)
Zikanova, A (EN)
Kortunov, P (EN)
Vasenkov, S (EN)
Glaser, R (EN)
Hansen, EW (EN)
Karger, J (EN)
Jirglova, H (EN)
Kocirik, M (EN)
Theodorou, D (EN)
Drescher, B (EN)
Bernauer, B (EN)
Krystl, V (EN)

conferenceItem (EN)

2014-03-01T02:43:29Z
2005 (EN)


Pulsed-field gradient nuclear magnetic resonance (PFG NMR) has been applied to study molecular diffusion in industrial fluid catalytic cracking (FCC) catalysts and in USY zeolite for a broad range of molecular displacements and temperatures. The results of this study have been used to elucidate the relevance of molecular transport on various displacements for the rate of molecular exchange between catalyst particles and their surroundings. It turned out that this rate, which may determine the overall rate and selectivity of FCC process, is primarily related to the diffusion mode associated with displacements larger than the size of zeolite crystals located in the particles but smaller than the size of the particles. This conclusion has been confirmed by comparative studies of the catalytic performance of different FCC catalysts. (c) 2005 Elsevier Inc. All rights reserved. (EN)

Radiology, Nuclear Medicine & Medical Imaging (EN)

particle size (EN)
comparative study (EN)
diffusion (EN)
pulsed field gel electrophoresis (EN)
crystal (EN)
catalysis (EN)
industry (EN)
Fluid catalytic cracking catalyst (EN)
Zeolites (EN)
fluid transport (EN)
temperature (EN)
Pulsed-field gradient (EN)
Nuclear magnetic resonance (EN)
priority journal (EN)
Catalysis (EN)
Diffusion (EN)
physical chemistry (EN)
Magnetic Resonance Spectroscopy (EN)
nuclear magnetic resonance (EN)
Particle Size (EN)
conference paper (EN)
zeolite (EN)
catalyst (EN)
molecule (EN)
Porosity (EN)

Magnetic Resonance Imaging (EN)

Αγγλική γλώσσα

ELSEVIER SCIENCE INC (EN)




*Η εύρυθμη και αδιάλειπτη λειτουργία των διαδικτυακών διευθύνσεων των συλλογών (ψηφιακό αρχείο, καρτέλα τεκμηρίου στο αποθετήριο) είναι αποκλειστική ευθύνη των αντίστοιχων Φορέων περιεχομένου.