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Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3 '-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks

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Synthesis of a halo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3 '-dimethyl-biphenyl linker using tris(halo-methylphenylene)triazines as building blocks
Monflier, Eric
Hanan, Garry S.
Andreadaki, Fotini J.
Κώστας, Ιωάννης Δ.
Medlycott, Elaine A.
Άρθρο σε επιστημονικό περιοδικό
2009-04-22
OXFORD
A tris(bromo-methylphenylene)triazine and its corresponding phosphine oxide derivative have been synthesized; the latter compound was found to be a potent ligand for the hydroformylation reaction. Suzuki coupling of the mono-pinacolboronate derivative of the former compound with a tris(iodo-methylphenylene)triazine was possible at two of the three iodine atoms, yielding a bromo- and iodo-methylphenylene periphery-functionalized triazine-based dendritic molecule with a 3,3 '-dimethyl-bipheny) linker.
Οργανική χημεία (EL)
Organic chemistry (EN)
Suzuki coupling
Dendrimer
Hydroformylation
Triazine
Cyclotrimerization
Phosphine oxide
English
Pergamon
Tetrahedron Letters
https://rightsstatements.org/page/InC/1.0/?language=en
© 2009 Elsevier Ltd. All rights reserved.
© 2009 Elsevier Ltd. All rights reserved. (EN)
National Hellenic Research Foundation (NHRF)
Helios - Repository of the National Hellenic Research Foundation (NHRF)



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