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Microwave assisted solid additive effects in simple dry chlorination reactions with n-chlorosuccinimide

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Microwave assisted solid additive effects in simple dry chlorination reactions with n-chlorosuccinimide
Μίχα-Σκρέττα, Μαρία
Σκρέττας, Κωνσταντίνος Γ.
Bucos, Madalina
Βιλλιαλονγκα-Μπαρμπέρ, Καρολίνα
Στηλ, Μπάρυ
Χαιρόπουλος, Γεώργιος Α.
Άρθρο σε επιστημονικό περιοδικό
2010-03-13
OXFORD
Solid additives participate in the dry microwave assisted chlorination reaction of N-chlorosuccinimide with the xylenes affecting both yields and chemoselectivities. Total yields can be increased up to nine times for simple alkylaromatics and chemoselectivities can be altered according to the desired ring or a-side chlorination product by choosing the appropriate additive. We believe that in these reactions the solid additives play a very important role by increasing yields and affecting chemoselectivities, as well as behaving as microwave energy absorbers that consequently aid the transfer of heat to the active reagents.
Οργανική χημεία (EL)
Organic chemistry (EN)
Dry halogenation
Passive heating elements
Microwave-assisted synthesis
Solid additives
N-Chlorosuccinimide
English
Pergamon
Tetrahedron
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© 2010 Elsevier Ltd. All rights reserved.
© 2010 Elsevier Ltd. All rights reserved. (EN)
National Hellenic Research Foundation (NHRF)
Helios - Repository of the National Hellenic Research Foundation (NHRF)



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