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New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigation

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New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigation
Tasiopoulos, A. J.
Soras, G.
Μούσδης, Γεώργιος Α.
Manos, M. J.
Psaroudakis, N.
Liakos, D. G.
Άρθρο σε επιστημονικό περιοδικό
2009-10-13
A new Nickel complex with an extended multisulfur dithiolene ligand Ni(edodddt)(2) (edodddt = 2,3,4 alpha,8 alpha-tetrahydro-dithiine [2,3-b] [1,4] dioxo-6,7-dithiolene) has been synthesized and characterized by electrochemical measurements, IR, UV-Vis and NMR spectroscopy. Its crystal structure was resolved by X-ray diffraction on a single crystal. DFT calculations were made in order to compare the results with the experimental findings and gain an insight of the properties of this new dithiolene complex.
Oxford
Κρυσταλλογραφία (EL)
Χημεία (Γενικά) (EL)
Chemistry (General) (EN)
Crystallography (EN)
Cyclic voltammetry
IR and Raman spectra
Chemistry, Inorganic & Nuclear
Dithiolene complexes
Ab initio calculations
Crystal structure
English
Pergamon-elsevier Science Limited
Polyhedron (incorporating Inorganic and Nuclear Chemistry Letters and Journal of Inorganic and Nuclear Chemistry)
https://rightsstatements.org/page/InC/1.0/?language=en
© 2009 Elsevier Ltd. All rights reserved.
© 2009 Elsevier Ltd. All rights reserved. (EN)
National Hellenic Research Foundation (NHRF)
Helios - Repository of the National Hellenic Research Foundation (NHRF)



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