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Preparation and characterization of Ni(dpedt)(pddt) and Ni(dpedt)(pddt)center dot CS2, where dpedt is diphenylethylenedithiolate and pddt is 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate

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Preparation and characterization of Ni(dpedt)(pddt) and Ni(dpedt)(pddt)center dot CS2, where dpedt is diphenylethylenedithiolate and pddt is 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate
Raptopoulou, Catherine P.
Παπαβασιλείου Γεώργιος
Terzis, Aris
Psycharis, Vassilis
Anyfantis, George C.
Paraskevopoulou, Patrina
Άρθρο σε επιστημονικό περιοδικό
2010-02-19
The unsymmetrical nickel 1,2-dithiolene complex based oil diphenylethylenedithiolate (dpedt) and 6,7-dihydro-5H-1,4-dithiepin-2,3-dithiolate (pddt) was prepared and characterized Depending on the conditions of crystallization, it is possible to obtain the complex in two different crystalline forms X-ray structure studies recognize these forms as Ni(dpedt)(pddt) and Ni(dpedt)(pddt) CS2 The experimental optical and electrochemical parameters are in a good agreement with the calculated ones. using the corresponding parameters of the symmetrical complexes. Ni(dpedt)(2) and Ni(pddt)(2). The HOMO and LUMO energy levels, obtained from optical and electrochemical measurements, are very close to the Fermi energy of (metallic) Au The chemical and electrochemical properties of both forms showed that they ale stable in air and could be candidate materials for optics and electronics
Oxford
Κρυσταλλογραφία (EL)
Χημεία (Γενικά) (EL)
Chemistry (General) (EN)
Crystallography (EN)
Chemistry, Inorganic & Nuclear
Metal 1,2-dithiolenes
Optical properties
Redox properties
Crystal structure
English
Pergamon-elsevier Science Limited
Polyhedron (incorporating Inorganic and Nuclear Chemistry Letters and Journal of Inorganic and Nuclear Chemistry)
https://rightsstatements.org/page/InC/1.0/?language=en
© 2009 Published by Elsevier Ltd.
© 2009 Published by Elsevier Ltd. (EN)
National Hellenic Research Foundation (NHRF)
Helios - Repository of the National Hellenic Research Foundation (NHRF)



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